From the Cards screen (second icon on the Vault section of the app), find the card that you wish to close. At the top right, you should see a vertical ellipses (three dots). Tap these three dots and select Close Card.
*Please note that this action is permanent and irreversible. You will need to order another card if you wish to have access to a new card. Replacement physical cards cost $4.00 and will be debited from your Vault account. Replacement virtual cards cost $0.10 after your first 2 virtual cards.*